冷拌冷铺超粘纤维磨耗层研究与应用

冷拌冷铺超粘纤维磨耗层作为一种新型技术,结合了微表处的材料特点和Novachip的施工工艺,具有优异的粘结性、防裂性、防水性、耐久性、环保性和经济性。本文从该项技术原理及性能要求、施工工艺及经济和社会效益进行了阐述。     

基于竹筋-钢筋骨架的人工假顶首层充填厚度研究及现场应用

采用简支梁理论、ANSYS软件数值模拟与现场试验相结合的方法,对竹筋-钢筋骨架人工假顶进行了可行性、受力行为、破坏方式与合理设计参数研究。结果表明,竹筋-钢筋骨架人工假顶结构可有效保护上部充填体,最优充填厚度为4.75 m; 采用竹筋-钢筋配筋方式可兼顾采场稳定性与经济效益,减少支护成本约15%。     

阳极导电材料对铁钨锡合金粉电解铁的影响

研究阳极导电材料碳素钢、316L不锈钢、铅钙合金、石墨、钛涂钌板、钛板和铜板在硫酸盐和氯盐体系中对铁钨锡合金粉电解铁的影响。结果表明:电解24 h,上述阳极导电材料在氯盐中的阴极电流效率为90%、90%、66%、66%、54%、49%、33%,在硫酸盐中的阴极电流效率为90%、87%、82%、81%、73%、68%、54%。槽电压均逐渐升高,在氯盐体系中,石墨、铅钙合金、钛涂钌板和钛板作阳极导电材料时,电解液pH逐渐降低;碳素钢、316L不锈钢和铜板作阳极导电材料时,电解液pH逐渐升高。在硫酸盐体系中,铜板和碳素钢作阳极导电材料时,电解液pH基本不变;316L不锈钢作阳极导电材料时,pH逐渐升高;铅钙合金、石墨和钛板作阳极导电材料时,pH先升高后降低。基于槽电压、阴极电流效率,选择适宜的电解体系为硫酸盐体系,该体系中适宜的阳极导电材料为铅钙合金。     

微型离心泵泵叶三层式滑块机构三板模具设计

针对微型离心泵泵叶塑件成型模具设计困难的问题，设计了一种改进型三板点浇口模以用于该泵叶塑件的成型。塑件的浇注成型应用3个点浇口来进行平衡注塑，以控制塑件成型变形。模腔布局为1模1腔。针对塑件叶槽区域脱模困难问题，设计了一种3层3次复合抽芯脱模用于难脱模叶槽部位特征的脱模，机构中，将叶槽部位特征的成型块分割成2层成型件后，机构的第一次抽芯动作由弹簧驱动上层滑块实施上层成型块的抽芯；机构的第二次抽芯由斜导柱驱动实施下层成型块的抽芯；最后，由弯销驱动基座滑块带动2个侧抽芯滑块向外抽芯，以让出塑件完全顶出脱模的运动空间。第二次抽芯、第三次抽芯的驱动动力分别由模架模板的第三次开模、第四次开模打开来进行驱动。塑件的最终脱模由油缸驱动顶针板及顶杆顶出而实现塑件的完全脱模。基于塑件、流道脱模及抽芯机构的动作需要，将典型三板点浇口模架改进为四板4次开模点浇口，从而能使塑件、流道废料及驱动滑块机构分次按序来实施抽芯脱模。模具脱模机构动作设置合理，机构结构设计巧妙，模具整体工作可靠，有较好的设计参考价值。     

A 1D High Performance Thin Layer Chromatography Method Validated to Quantify Phospholipids Including Cardiolipin and Monolysocardiolipin from Biological Samples

The aim of this study is to identify high performance thin layer chromatography (HPTLC) conditions allowing the separation and quantification of mammalian cellular phospholipids (PLs) (sphingomyelin, phosphatidylcholine, phosphatidylserine, phosphatidylinositol, phosphatidylethanolamine, and especially phosphatidic acid, cardiolipin, and monolysocardiolipin, these latter two being specifically located in mitochondria membranes). In order to make this method faster and easier, a 1D HPTLC method is chosen, testing several eluents as well as several staining methods. A pre‐conditioning of HPTLC plates with boric acid and a copper staining reagent followed by carbonization are selected for the quality of PL separation and homogeneity of staining. The selected conditions are discussed and the method validation is performed according to the International Conference on Harmonization guidelines. Linearity is effective between 1 and 8 µg and limit of quantification is between 0.5 and 2.3 µg depending on PL classes. Precision measurements show coefficients of variation <6%, and when amounts are close to the detection limit, <12%. Lipid extracts of tumor cell lines or isolated mitochondria are used to assess PL profiles. This shows that the HPTLC method can be used routinely to follow level variations of PLs. Practical Applications: The changes in PL composition play a crucial role in tumor processes and regulate cellular functions modulating cellular signaling or mitochondrial metabolism. The simple and cost‐effective 1D HPTLC method that is developed is applied to lipid extracts of whole tumor cells or hepatocyte‐isolated mitochondria. It is sensitive as well as precise to detect variations of phosphatidic acid or cardiolipin levels linked to physio‐pathological conditions. It can also be used to investigate the composition changes of other membrane PLs. Moreover, with a simultaneous analysis of 14 samples/standards on the same plate (six plates per day), this method is adapted for large series of samples.     

高边坡开挖卸荷过程强度折减法分析

针对露天矿开采过程中边坡变形破坏严重影响露天矿安全生产的问题，采用数值模拟的方法，应用MidasGTS NX软件建立重钢太和露天铁矿黄家山高边坡三维模型，进行开挖卸荷过程中的应力应变、位移及安全系数变化的数值模拟分析。结果表明：边坡岩体开挖卸荷过程中，随着采场的延深，边坡角的增大,塑性应力带的逐渐向边坡岩体内部扩大，风化破碎层及上部冰碛土层之间产生塑性应变贯通区，破坏面形成。开挖完成后整体边坡坡脚处发生剪切破坏，坡顶后缘形成张拉破坏区，边坡上部冰碛土层形成 “坐落—滑移”式滑动。边坡安全系数随向下开挖过程逐级降低，最终达到1.15稍显偏低。后期开采过程中，需对边坡中上部风化破碎岩层及冰碛土进行加固措施。     

煤层软硬分层吸附瓦斯性能差异性及其对瓦斯赋存的影响

为研究煤层软、硬分层吸附瓦斯性能差异性及其对瓦斯赋存的影响,分析了煤层内软分层的形成机理及结构特征,采集了我国多个煤与瓦斯突出矿井的煤样作为试验对象,应用高压容量法开展了软、硬分层煤样吸附瓦斯性能参数的对比试验,探讨了软煤、硬煤吸附性能的差异性。在此基础上,对煤层软、硬分层吸附瓦斯性能差异性与瓦斯赋存特征之间的关联进行了研究,结果表明:试验煤样软分层的极限吸附量均大于硬分层;随着瓦斯压力的增加,试验煤样软、硬分层瓦斯含量的差值逐渐增大,其曲线的变化特征与Langmuir方程类似,并且软、硬分层瓦斯含量数值的差异主要由吸附量差值构成;煤层软、硬分层吸附瓦斯性能的差异不仅对煤层原始瓦斯赋存特征有着显著的影响,同时还将影响煤巷掘进、瓦斯抽采过程中煤体内瓦斯流场的分布规律,需要根据煤层软、硬分层的组合特点,制订切实有效的瓦斯抽采技术方案。     

Current-ramp assisted sintering of 3YSZ: Electrochemical and microstructural comparison to flash and thermal sintering

Flash sintering features an unoptimized and uncontrolled rise in current density and sample conductivity. By using a controlled current-ramp technique with a predetermined ramp function, microstructure and electrochemical properties can be improved. This current-ramp method is investigated through use of test functions that follow square-root, linear, and parabolic time dependence with comparison to conventional flash sintering and thermal sintering. Steeper ramp functions during the sintering result in higher activation energy, suggesting a change in the vacancy concentration for both the bulk and grain boundary regions. Estimation of the grain boundary domain width suggests a grain size dependence of the unique space charge contribution to conduction independent of sintering method. Contrary to conventional wisdom, flash sintering can actually result in enhanced grain growth compared to controlled current-ramps and conventional sintering, implying that uncontrolled rise in current to a set cutoff may not be the optimal method for densification.     

A strategy to reduce the impact of tar on a Ni‐YSZ anode of solid oxide fuel cells

High‐temperature raw coke oven gas (COG) is a promising fuel for use in solid oxide fuel cells (SOFCs) because it is rich in both hydrogen (55%‐60%) and methane (23%‐27%). However, the tar present in COG limits its ability to directly generate power using state‐of‐art SOFCs because the presence of tar limits the cell's performance and stability. In this work, a strategy is presented in the attempt to reduce the influence of tar on SOFCs by applying a La_0.7Sr_0.3MnO₃ catalyst as a protective layer for the cell. The results showed that 44‐g Nm^?3 toluene had a profoundly negative effect on the performance of a conventional cell, which showed severely reduced performance after only 1.4 hours of exposure to toluene‐contaminated hydrogen. In contrast, the catalyst‐modified cell showed good stability for at least 110 hours under the same conditions. This work provides a promising route to directly utilize raw COG as an SOFC fuel that is also suitable for biosyngas.     

Turbulent heat transfer characteristics of supercritical n‐decane in a vertical tube under various operating pressures

To explore the effect of the operating pressure on the flow and thermal characteristics in a vertical tube with supercritical n‐decane, the inner wall temperature along the streamwise direction, the applicability of empirical correlations and buoyancy criteria are studied firstly. The mechanisms in views of density distribution, velocity field, turbulence intensity, the thickness of the thermal boundary layer, and secondary flow are then analyzed. It is observed that the buoyancy is helpful for the phenomenon of heat transfer deterioration at lower operating pressures but higher operating pressures can diminish this tendency. According to this reason, the empirical correlation proposed by Bae and Kim is suitable for the higher operating pressures but cannot well predict the occurrence of heat transfer deterioration. However, it can be evaluated by the buoyancy criterion Gr/Re² = 0.01 qualitatively. The decrease of turbulence intensity, the thickened thermal boundary layer, and secondary flow generation make contributions to the heat transfer deterioration in particular. Similarly, this situation can be diminished and even removed by the higher operating pressures.